27.
Use the sp3 model and then the sp2 model to predict what would happen
to the double bond when the two ends of the ethylene molecule are
twisted9 How does the real molecule behave, and which model is most
compatible with reality?
28. Sketch the o--bond skeleton of the ethylene molecule.
Draw in the p MO of the second bond.
What is the electron probability density at each of the six atoms
in ethylene from the electrons in this p
MO? Draw the nodal surface for this orbital.
29. Sketch the s-bond skeleton
of the acetylene molecule. Draw in the p
MO's of the second and third bonds between carbon.
30. How does the carbon-carbon bond length change between
ethane, ethylene, and acetylene? How would you expect the bond energies
to change?
31. Sketch the s-bond skeleton
of the benzene molecule. How many AO's and how many bonding electrons
are used in this s- skeleton? What kind
of hybridization is used around the carbon atoms?
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