In the first example, electrons are physically removed from
copper atoms to produce positively
charged copper ions. In the
second example, electrons on hydrogen that originally were
shared equally with another hydrogen atom are partially lost
by being shared unequally with oxygen atoms. Since electrons
are never created or destroyed in chemical reactions, whenever
one atom is oxidized, another atom must be reduced
.When hydrogen is oxidized by the process above, oxygen is
reduced. The copper reaction is incomplete, since some unspecified
substance must become reduced by taking up the two electrons
indicated on the right side of the equation.
In the water reaction, hydrogen is oxidized and oxygen is
reduced. Free energy is given off because oxygen is a strong
oxidizing agent (meaning that it has a strong attraction for
electrons) and hydrogen is a good reducing agent (meaning
that it lets go of its electrons easily to something else).
The standard free energy change during this reaction is D
G° = -54.6 kcal mol-l of water vapor. In general, the
oxidation of a substance with a tenuous hold on its electrons,
by a strong oxidant with a powerful pull for electrons, is
accompanied by the release of free
energy. It is a spontaneous
process.
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