Delocalization has appeared
several times in previous chapters, but only now can we give it
an interpretation in terms of molecular orbitals. The benzene molecule
was introduced in Chapter 4, and the carbonate and nitrate ions
in Chapter 5. The various Lewis dot models for CO,
which assigned single- or double-bond character to different combinations
of the three C-0 bonds, were resonance structures for the carbonate
ion, differing only in the positioning of electrons between atoms.
The phosphate, sulfate, and perchlorate ions discussed in Chapter
6 also were examples of delocalization. In all of these examples,
delocalization brought extra stability to the ion, and it is a good
practical rule of thumb that the more resonance structures one can
draw for a delocalized ion or molecule, the more stability this
delocalization creates.