The
energy-level diagram for these six MO's appears at the right. As
we have seen consistently in other AO's and MO's, the general principle
holds that, other things being equal, the more nodes of zero probability
in an orbital, the higher its energy. Six p atomic orbitals are
combined to form six molecular orbitals-three bonding and three
antibonding. The six electrons not used in the o, framework of the
benzene molecule are used to fill the three bonding MO's, and the
antibonding orbitals are unused. The benzene ring therefore has
three more bonds in addition to its s-bonded
skeleton, but these three bonds are spread around the entire ring
rather than being localized between pairs of carbon atoms, as the
Kekule or Dewar models would predict. All of the carbon-carbon bonds
in the ring are intermediate between "single" and "double," and
their observed bond length verifies this.