Magnetic Moments
and Unpaired Electrons


Paramagnetic species, i.e. those with unpaired electrons, are attracted by a magnetic field. We can measure the strength of the attraction, and thereby calculate the magnetic moment of the sample; and from the latter we can infer the number of unpaired electron spins present.

The magnetic moment m is approximately related to the number of unpaired electrons n by the formula:

m = [n(n + 2)]1/2 B

Where B is the Bohr magneton, the atomic unit of magnetic moment.

Derivation of this formulaReturn to the menu