The energy needed to make the same number of isolated atoms
from graphite and H2
gas is
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The difference between these two numbers should be the heat
of formation, as shown below:
DH0
= 1343 - 1283 = +60 kcal per mole of benzene
By this calculation, heat is absorbed, not emitted, when benzene
is formed from its elements. We encounter trouble as soon
as we try to compare this calculated value of +60 kcal mole-1
with reality. It is true that heat is absorbed when benzene
is made from carbon and hydrogen, but only 20 kcal mole-1,
not 60.
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