Just
as when a salt crystal dissolves, each ion is thoroughly hydrated
by being surrounded by three or four water molecules. Each proton
is surrounded by water molecules with their negatively charged oxygens
pointed toward it, and each fluoride ion is surrounded by other water
molecules with hydrogens pointed at it (see right). Since water molecules
are involved in the pulling apart or dissociation of HF, the preceding
reaction really should be written
HF + (n + m) H20
----> H+ (H20)n
+ F-(H20)m
The subscripts n and m represent the number of water molecules that
can be accommodated around each ion. This is 3 or 4 for these small
ions, but for larger ions, n and m can be 6 or even greater. This
is another example of how a polar liquid such as water is a good solvent
for other polar substances or for salts with charged ions. A more
general term for hydration when the solvent is a liquid other than
water, such as liquid ammonia, is solvation.