Fluorine
is the only element that is more electronegative than oxygen. It is
the only substance which, when combined with oxygen, pulls the bonding
electron pair away from oxygen and toward itself. It has seven electrons
in its outer shell and needs only one more to complete the stable
octet. Fluorine gas consists of F2
molecules with a single F-F bond between atoms.
Its hydrogen compound is hydrogen fluoride, HF, in which the F atom
is surrounded by three lone pairs and one bonding pair (see right).
The H-F bond is more polar than the H-O bond, being 41% ionic compared
with 33%. But because HF has only one polar bond, whereas H20
has two, the overall dipole moment is smaller, 1.82 D compared to
1.85 D for water. With only one proton, HF can make only one hydrogen
bond to another molecule, so the liquid is not as tightly "stitched"
together as water is. Therefore HF boils at 19C, whereas water boils
at 100C (both values at 1 atm pressure). Neither ammonia nor HF can
form the elaborate open-cage structures found in ice. Ammonia can't
because it has only one lone pair available for receiving a hydrogen
bond, and HF can't because it has only one proton with which to make
a hydrogen bond. Water has the fortunate combination of two protons
for hydrogen bonding and two lone pairs to receive such bonds from
neighbors. The result is the three-dimensional framework structure
of ice.