In Chapter 10 a negative free energy
change was used as a criterion for spontaneity. The standard free
energy change, (298)
is the free energy of the reaction with all substances at 298K,
all gases at partial pressure of 1 atm, and all dissolved substances
at concentration of 1 mole per liter. This standard free energy
change and the equilibnum constant are related by the above expressions
.
A large negative standard free energy change for a reaction indicates
a large value for ,
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and a large positive standard
free energy change means an extremely small value for .
If
= 0.000, then
= 1.000.
In Chapter 13 we answered the question as to when a reaction
would, or would not, be spontaneous and moving toward equilibrium.
This chapter dealt with the matter of just how far a reaction
would go before it arrived at equilibrium, but still said nothing
al'out the time needed to get there. The next chapter will answer
this final question: How fast will a chemical reaction go?
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