7. The ionization constant for arsenous acid (HAsO2)
is 6.0 x 10-10. What is the PH of a 0.10-molar solution
of arsenous acid? What is the pH of a 0.10-molar solution of NaAsO2?
8. A solution of ammonia has a hydrogen ion concentration of 8.0
x10-9 mole per liter. What is the pOH of this solution?
9. What is the CN- ion concentration and the pOH in
a 1.00-molar aqueous solution of HCN?
10. Pyridine is an organic base that reacts with water as follows:
C5H5N + H2O = C5H5NH+
+ OH-
The base-dissociation constant for this reaction, Kb,
is 1.58 x 10-8. What is the concentration of C5H5NH+
ion in a solution that was initially 0.10 molar in pyridine? What
is the pH of the solution?
11. What is the equilibrium concentration of NO2-
ion in a 0.22-molar aqueous solution of nitrous acid? What is the
pH? What is the percent ionization of HNO2?
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12. Hydrazine is a weak base that dissociates in water according
to the equation
N2H4 + H2O = N2H5+
+ OH-
The equilibrium constant for this dissociation at 25'C is 2.0 X
10-6. Write the equilibrium-constant expression for this
reaction. If the initial hydrazine concentration is 0.010 molar,
what is the concentration of hydrazinium ion, N2H5+
? What is the pH?
13. What is the pH of a 0.18-molar solution of ammonium chloride?
14. What is the pH of a 0.025-molar solution of sodium acetate?
15. What is the pH of a 1.0-molar solution of sodium cyanide?
16. A buffer solution is made with 0.30-molar sodium cyanide and
0.30-molar HCN. What is the pH of the buffer solution?
17. What is the pH of a buffer prepared to be 0.20 molar in NH3
and 0.40 molar in NH4Cl?
18. A buffer solution is made from equal volumes of 0.10-molar
acetic acid and 0.10-molar sodium acetate. What is the pH of the
buffer?
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