
The first-order
rate
law for the decay of carbon-14 nuclei,
is a differential equation. It tells us how the
change in with time depends on . It would be desirable to have another expression
that simply told how the varies with time in a first-order decay process:
|
[C-14] = some function of t |
Elementary calculus shows us how we can derive
an expression for concentration versus time from a rate equation, using
the process of integration. The general method is beyond the scope of this
chapter, but we can give the result for a first-order decay:
Starting from an initial concentration at time
t = O of [C-14]o the concentration of
carbon-14 at some later time, t, decreases exponentially, as shown above.
One property of exponential decay is that, if after a certain time interval
the has fallen by half, then after another interval of equal length the
concentration will have fallen by half again, or to one quarter its original
value.
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