For , fluoride
ions as ligands cause such a small splitting that the six outer
electrons in
can spread out among both levels to produce a high-spin complex
with four unpaired electrons (see right).
absorbs radiation of low energy red wavelengths, and thus is green.
Ammonia is a stronger ligand, and produces a large enough splitting
to keep all six
electrons paired in the ,
, and
orbitals, which point away from the lone pairs of the ammonia nitrogens.
When electrons are promoted to the upper e state in
blue light is absorbed, thereby giving solutions of the complex
a yellow-orange hue. Because the cyanide ion, ,
is a strong ligand, capable of producing a large splitting, absorption
for occurs
in the ultraviolet. The small tail of absorption extending into
the violet region gives
solutions a washed-out yellow cast.