An s and a p orbital as in (c)
cannot be combined, because they have different bond-axis symmetries.
Any positive overlap between the s and the upper lobe of the p would
be canceled exactly by negative overlap between s and the bottom
lobe, and nothing would result. If the p orbital is turned 90 degrees
so one lobe points toward s along the bond axis as in (d), then
both AO's have s symmetry along the bond axis. They can be combined
without canceling, provided the similar-energy requirement is met.
|
|
With these three principles, we
are now ready to build MO's from the 2s, 2p ,
2p and
2p atomic
orbitals of two atoms. The two 2s orbitals are added and subtracted
to produce bonding and antibonding MO's in the way seen previously
for H
=2s+2s =2s-2s
|