Lecture
1 |
Review
of course content and requirements. General comments on the atomic and
chemical properties of non-metals elements; feasibility of cation and anion
formation; trends in bond energies and their relevance to non-metal chemistry. |
Lecture
2 |
Boron structures
of elemental boron and some borides; boron-nitrogen compounds; boron halides,
boron oxides and borates; boron hydrides; - an introduction. |
Lecture
3 |
Carbon catenation;
comparison with silicon; chemistry of the elements; carbon monoxide as
a ligand, p-acidity;
the halides - the importance of thermodynamic versus kinetic stability. |
Lecture
4 |
Nitrogen
general comments - the importance of lone pair repulsion
in N-X single bonds; thermodynamic instability of many nitrogen compounds;
dinitrogen complexes; nitrogen hydrides; the nitrogen halides; nitrogen
oxides. Comparison with phosphorus. |
Lecture
5 |
Oxygen
dioxygen and ozone; the hydrides - hydrogen bonding; structural and acid/base
classification of oxides of the elements. Comparison with sulphur. |
Lecture
6 |
The Halogens
the haloacids, oxides, oxoacids, oxoanions and their redox
properties; the interhalogens. |