Physicists worry about the contrast between the obviously irreversible,
one-directional nature of time in the macroscopic world, and the
apparent complete reversibility of all of the laws of mechanics.
Any molecular collision or reaction can take place equally well
in a forward or a reverse direction.
If we were able to make molecular scale "home movies" of any atomic
process, we would have no clue from the movie alone as to whether
it was being run forward or backward . If the forward process was
a reaction of molecules of H2 and
I2 to form two HI molecules, the
reverse process would be equally possible collision of two HI molecules
to form H2 and I2.
One would have no basis for defining a "positive sense" to the
flow of time at the molecular level. This is known as the principle
of microscopic reversibility in physics and chemistry: On the
molecular scale, if a forward reaction is possible, the reverse
reaction must be equally possible.
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In contrast, the positive direction of time presents no problem
at the level of the macroscopic world. Movies run backward are considered
hilarious just because they violate common sense so completely.
At the top of the next page is a series of frames representing the
simple operation of dissolving ink in water.
At the bottom of the page are the same frames in reverse order.
We have no difficulty in saying that the top order is right and
the bottom order is wrong. But what is the basis for this decision?
The basis is our deeply ingrained, intuitive realization that order
can lead to chaos, but chaos never spontaneously produces order.
Beginning students sometimes feel that entropy is an abstruse concept,
but we all appreciate what it means even before we put a name to
it.
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