The
formation of a water molecule, H-O-H or H2O,
is shown at right. The two lone pairs repel one another, and each
repels the bonding pairs more than the bonding pairs themselves repel
one another. The H-O-H angle therefore is squeezed down from an ideal
tetrahedral angle of 109.5 degrees to 105 degrees. Oxygen is more
electronegative than nitrogen, so each O-H bond has 33% ionic character,
whereas the N-H bond in ammonia has only 27% ionic character. This
plus the presence of two lone electron pairs on O increase the dipole
moment of the molecule as a whole to 1.85 D, to be compared with 1.47
D for ammonia. Each hydrogen atom in water has a partial positive
charge, and the oxygen atom has a partial negative charge. An H20
molecule is a miniature dipole.