The
unit of measure for dipole moments is the debye (abbreviated D) .
A proton and an electron held 1 A apart would constitute a dipole
moment of 4.8 debye. (The 4.8 factor has no deep significance, but
merely comes from the size of the charge on an electron. ) Methane
has no dipole moment, and ammonia has a dipole moment of 1.47 D. Water
is slightly more polar, with a dipole moment of 1.85 D. If lithium
fluoride salt is vaporized at temperatures above 1676C, the gaseous
LiF molecules have the quite large dipole moment of 6.33 D. In the
preceding chapter we said that most real bonds were intermediates
between the extremes of completely covalent and totally ionic. Measured
dipole moments allow us to calculate the percent of ionic and covalent
character of a bond. Since two charges of +1 and -1, located 1.0 A
apart, yield a dipole moment of
u = 4.8 D, we can write
u = 4.8 qr
with q in units of electron charge and r in angstroms. The atoms in
an HF molecule are 0.92 A apart, and the measured dipole moment is
1.82 D. Hence,
1.82 = 4.8 x 0.92 q
q = 0.41 of the charge on an electron