In Steps d and e of the catalytic mechanism, the same proton does
not have to move bodily from one oxygen atom to the other. It can
transfer to a nearby water molecule and cause that molecule to donate
one of its protons to the bridge oxygen. Proton transfer in aqueous
solution is faster and easier than any other kind of atom shift.
Any compound that has lone electron pairs on an electronegative
atom can attract a proton in acid solution. This includes almost
every type of organic compound. A proton can also be attracted to
the electrons of a double bond and catalyze the addition of HBr
or some other substance across the bond:
There are few reactions of carbon compounds that acid will not
catalyze. This is why we have hydrochloric acid in our stomach,
to help enzymes digest and hydrolyze proteins. This is also why
acid catalysis is so important in the chemical industry, from synthesis
of rubbers and organic dyestuffs to pharmaceutical compounds.